174. Cousins, S. K., and R. M. Brown, Jr. 1997. Photoisomerization of a dye-altered ß-1, 4 glucan sheet induces the crystallization of a cellulose-composite. Polymer. 38: 903-912

174. Abstract

Dye-altered ß-1,4 glucan sheets synthesized by the bacterium Acetobacter xylinum in the presence of the fluorescent brightener Tinopal LpW were induced to crystallize into cellulose microfibrils by a novel photoisomerization of the dye molecules. Reducing the rate of dye removal led to more uniform microfibril dimensions, narrower ribbon width, and a greater microfibril helical pitch. The induced microfibrils are theorized to represent a composite of parallel glucan chains with dye molecules intercalated and deforming the cellulose lattice. It is speculated that during cellulose synthesis in general, glucan minisheets could associate by a constriction in the extrusion pore of the cellulose synthase complexes.

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